No. An XLL expression supports a chain of locators, each of which
starts from the last place you got to in the target document's
structure. You can have a second chain, pointing to somewhere else, in
which case the XPointer is deemed to point to the span witihn the
document whose end-points are the two elements or characters you have
specified by your locators.
I've just checked over the original TEI Extended Pointer mechanism on
which XPointers are based, and there is nothing in that to support
boolean logic either.
Richard Light
SGML/XML and Museum Information Consultancy
richard@light.demon.co.uk