Table S1.
The Observed Rates of Hydrolysis of 1 in Aqueous Hydrochloric Acid.
[HClO4] / M Rate / s -1
0.0001 0.000797, 0.00133, 0.00142
0.0006 0.00960, 0.00947, 0.00896
0.001 0.0146, 0.0153, 0.0148
0.004 0.0654, 0.0634, 0.0629
0.01 0.155, 0.158, 0.147
Table S2.
The Observed Rates of Hydrolysis of 3 in Aqueous Hydrochloric Acid.
[HClO4] / M kOBS / s-1
0.1 0.00244, 0.00239, 0.00245,0.00244
0.04 0.000990, 0.000975, 0.000979
0.01 0.000241, 0.000251, 0.000254
0.004 9.84e-005, 9.87e-005, 9.759e-005
0.001 2.08e-005, 1.99e-005, 2.07e-005
Table S3.
The Observed Rates of Hydrolysis of 1 in DClO4 / D2O solutions
[DClO4] / M Rate / s-1
0.00021 0.000224, 0.000203, 0.000243
0.00124 0.00699, 0.00677, 0.00668
0.00414 0.0253, 0.0272, 0.0265
0.01035 0.0664, 0.0678, 0.0674
Table S4.
The Observed Rates of Hydrolysis of 3 in DClO4 / D2O solutions
[DClO4] / M Rate / s-1
0.1035 0.0106, 0.0101, 0.0106
0.052 0.00474, 0.00494
0.01 0.000984, 0.000944, 0.000935
0.00414 0.000367, 0.000371, 0.000366
0.00124 7.98e-005, 8.58e-005, 8.69e-005
Table S5.
The Observed Rates of Hydrolysis of 3 in the Presence of Iodide-ion
and [H+] = 0.01 M
[I-] / M Rate / s-1
0 2.41e-004, 2.51e-004, 2.54e-004
0.1 3.72e-004, 3.70e-004
0.3 5.22e-004, 5.33e-004
0.5 7.14e-004, 6.92e-004
0.7 8.74e-004, 8.75e-004
0.9 1.06e-003, 9.56e-004